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If the formation to be acidised contains significant quantities of soluble ferric iron (Fe3+) as opposed to ferrous (Fe2+), solids can be precipitated as the acid spends. Ferric iron precipitates at about pH 2.2, ferrous at about 7, so as 'spent' acid rarely reaches a pH of more than 6, precipitation of ferrous iron is seldom a problem. The gelatinous precipitate of ferric hydroxide can cause a reduction in permeability in the well, in some cases to below that of the well before treatment. This precipitation can be prevented by the use of complexing or sequestering materials.
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